Recent developments of thermoelectric power generation
鞣鼹甏l醛瓣黪
C打ineseScienceBulletin2004V01.49No.121212—1219
Recentdevelopmentsof
thermoelectricpower
generation
LUAN
Weiling&TUShantung
East
ChinaUniversityofScienceandTechnology,Schoolof
Mechanical
Engineering,Shanghai200237,ChinaCorrespondenceshouldbeaddressedto
Luan
Weiling(e-mail:luan@
ecust.edu.cn)
Abstract
0neformofenergygenerationthatisexpected
tobe
on
therise
inthenextseveraldecadesisthermoelectric
power
generation(TEPG)whichconvertsheatdirectlyto
electricity.Comparedwithothermethods,TEPGpossessesthesalientfeaturesofbeingcompact,light-weighted,noiselessinoperation,highlyreliable,freeofcarbondioxide
emissionandradioactivesubstances.Lowcurrentconversionefnciency
andhighcost.however,
are
some
ofthe
disadvanta2es.UseofTEPGisthereforejustifiedtohightechapplicationsassociatedwithaerospace,militaryoperation,
tel.communication
and
navigation。
instrumentationofunmannedvehiclesmonitoredfromremotelocations.More-over.TEPGdoesnotcontHbutetothedepletionofnatural
resource
andpollutionoftheenvironmentsuch
as
climate
warmingthathasbeenaconcerninrecenttimes.ThisworkisconcernedwithprovidinganoverviewofthestateoftheartofTEPGwithemphasesplacedonassessingitscurrentandpotentialapplication.Pointedoutarethewaystofabri-cate
high
performancethermoelectricmaterial。ahurdleto
overcomefortheenhancementofTEPGdeviceemciency.
Keywords:thermoelectricpowergeneration,thermoelectricmaterial,
electricpower,thermoelectricsensor.
Thesearchfor
green,compact.10ng-lasting,
low..maintenancecommercialmethodsofgeneratingelec..trical
powerhasincreasedin
priority
as
thepublic
be—
comesmoreawareofenergyconservationandenviron—
mentprotection.Fuelcellsandotheralternativesarecur—
rentlybeinginvestigated.They.however,encounter
diffi—
culties
inpracticalapplication.Comparativelyspeaking,
TEPGhasbeenrecognizedasoneofthemajorenergYconversion
technologies,mainlybecauseoftheadvan—
tagesmentionedearlierwhichincludecompactsize,lightweight.noiselessnessandnoemission.TheUS0fficeofSpace&DefensePowerSystemsregardsTEPGasaprovenmethodforenergygenerationintermsofsafety,reliabilityandmaintainabilitv.Itisalsocapableofpro—
ducingeitherheator
electricityforlongperiodsoftimemeasurableindecades
under
hazardnessconditions
en—
counteredin
outer
space“.Therecentrecognitionwas
arisenthatTEPGdevicesarealsocost—effectiveifenvi—
ronmentistakenintoaccount.Thismakesthemethod
attractiveforthegenerationofelectricityinadditiontoitssuperiorfeaturesforapplicationinthehigh—techfieldsin—volvingspecializedmedicine.spaceandmilitaryuselilJ.ResearchanddevelopmentofTEPGhasbeenrecog—
nizedinmanydevelopedcountriesas10ngtomid—termscientificprograms.USAaimsprincipallyatitsapplica—tioninmilitary.spaceandhigh—techareas.TheJapanesegovernmentisfundingTEPGresearchinretrievingwaste
heat
emitted
from
automobiles,factoriesandsimilar
sources.The
EuropeanUnionfocusesattention
onlow.powergenerationandsensors.Chinamakesachieve.mentsoncoolingtheoryandtheproductionofthermo.
electricsemiconductorsalthoughwithlessemphasesonpowergenerationforthepresent.Thoughseveraloversea
companiesbuiltplantsinShanghai.Hangzhouandother
cities,theexplorationofthistechnologyandproductare
stilllackingo’1“.1
Mechanism
ofthermoelectricpowergeneration
Conversionofheatdirectlyintoelectricityisnot
a
newprinciple.Itwasdiscoveredin1822byaGerman
scientist,ThomasSeebeck.Heobservedthatan
electric
voltage
is
generated
when
twodissimilar,electrically
conductive
materials(iron
and
copper)areioinedina
closedcircuitandthetwo1unctionsarekeptatdifierenttemperatures.Suchpairsof{unctionsarecalledthermo.
electriccouples,andthephenomenonobservediscalledSeebeckeffect.
TheschematicofTEPG
isillustratedinFig.1.A
typicaldeviceiscomposedoftwoelectricallyconducting
Fig.1.SchematicdiagramofmulticoupleThermoelectricGeneration
Modules.
1)U.S.DepartmentofEnergy.AdvancedRadioisotopePowerSystems,http://nuclear.gov/space/arpsfact.pdf,20021212
∞inese
ScienceBulletinV01.49No.12June
2004
materials:onecalledN—typeandtheotherP—type.N—typematerialisdopedsothatitwillhaveanexcessofelectrons(moreelectrons
thanneededtocompleteaperfectmo—
lecularlatticestructure)andP—typematerialisdopedsothatitwillhaveadeficiencyofelectronsffewerelectronsthannecessarytocompleteaperfectlatticestructure).TheextraelectronsintheN—materialandtheholesresultingfromtheP—materialarethechargecarriers.Thesetwokindsofmaterials
are
connectedelectricallyinseriesby
highlyconductingmetalstripsandsandwichedbetweenthermallyconductingbutelectricallyinsulatingplates.Astheheatmovesfromthehottothecoldplate,thechargecarriersarecarriedwimtheheat.Heatalsoaffectschargecarriermovementinthereturnpathftypicallycopperwire).Becauseelectronsflowin
a
directionoppositeto
thatofhole.thecurrentgeneratingpotentialsinthepelletsdonotopposeoneanother,butareseries—adding.Theheat
movementinsemiconductormaterials
can
carryfarmore
chargecarriersthanthatofthereturnpathofacircuit.
Therefore.asignificantpotentialdifference(i.e.Seebeckvoltage)isgenerated.BylinkingtogetheralargenumberofthermoelectricPandNcouples,asizeablevoltagecanbegenerated.CommerciallyavailableTEPGcontainsl8
—128
couples.Thepoweroutputdepends
on
thermoelec—
tricmaterial’s
properties
and
the
temperature
gradient
betweencoldandhotends.
InTEPGelectricalchargecarriers(electronsorholes)
insteadoflatticearetheenergytransportmedia.Thereisno
needofmechanicalcomponentsorhazardousworkingfluidsduringthewholeprocess.Therefore,TEPGoffers
severaldistinct
advantages
over
other
technologiesin—
volving
no
movingparts
or
bulkfuids,lowmaintenance,
lightweight,novibration,noopticandsonicsignal,andflexibilityonheatsource.2
ApplicationsofthermoelectricpowergenerationThe
firstTEPGunitwasbuiltintheformerSovietUnionin
1942with
an
efficiency
of
1.5%一2%.In
the
l960s.theresearchinthisarea
wasintensifiedand
a
series
of
thermoelectric
devices
weremade
successfullyand
appliedinmilitarymissionsinvolvingremotetel_。com。。municationandnavigation.Duetothemorerecentcon—
cemofenergyandenvironmentcrisis,addedvaluewasgiventotheuseofTEPG
(i)Exploration
ofspace.TEPGhasprovided
continuouspowersafelyandreliablyoverthepastthreedecadesinregionsofspacewheretheuseofsolarpower
isnotfeasible.TheUSDepartmentofEnergy(DOE)hasusedTEPGforspaceformanyyearsLl“.TheApollo(tothemoon),Viking(toMars),Pioneer,Voyager,Ulysses,Galileo.andCassini(outerSolarSystem)missionsallusedTEPGs.TheTEPGsforthePioneer10spacecrafthaveoperatedflawlesslyfor30yearsandcontinuetopowerthe
spacecraft
as
ittravelsbeyond
Pluto.During
黢鹾Vl鼹暇翁
lastthreedecades,theUnitedStateshaslaunched25mis—sionsinvolving44TEPGs。whileTEPGshavenever
been
the
cause
of
a
spacecraftaccident.
TEPGdevicessupplyhundredsofwattsofelectrical
powerforspacecraftbydirectconversionoftheheatgen—eratedbythenaturaldecayofradioisotopematerials.SuchTEPG
is
thereforecalledRadioisotope
Thermoelec:tric
Generator(RTGl.RTGconsistsoftwomajorelements:aheatsourcethatcontainsdecaymaterials(Plutonium一238)
and
a
set
ofsolid—statethermocouples.Fig.2illustrated
thestructureofRTGanditsGeneralPurposeHeatSourcemodulesusedonspacecraft.
Fig.2.RadioisotopeThermoelectricGenerator(upper)andGeneral
PurposeHeatSourcemodules(10wer).
Nowhuman
being’sexploration
is
heading
to
heliopause.theboundarywheretheSun’sinfluenceendsandthedarkrecessesofinterstellarspacebegin.Togetabove
the
Sun,Ulysses
has
to
fly
aroundJupiterand
slingshotoutoftheplaneoftheplanets.NearJupiter,theSun’sraysare25timesweakerthanthoseneartheEarth.SolarpanelslargeenoughtocatchthisweakenergYwouldhaveweighedl200pounds.doublingtheweightofthespacecraftandmakingittooheavyforboosterrocketsfromtheshuttle.Instead,Ulysseswasequippedwithan
I汀G
weighingonly124pounds.Iteasilypowersallthe
probe’sonboardsystems,includingnavigation,communi—cationandscientificinstruments¨.
TheDOEandNASA
are
initiatingthedevelopment
of
a
newgenerationofpower
system
thatcould
be
usedfor
a
variety
ofmissions.ThenewRTGcalled
Multi—MissionRadioisotopeThermoelectricGeneratorfMMRTG),willbedesignedtooperateon
planetary
11
u.s.OfficeofSpace&DefensePowerSystems,Radioisotopepowersystems.http://nuclear.gov/space/gphs.html,2003
ChineseScienceBuliet/n
V01.49
No.12
June
2004
1213
Fig.3.
5000
WTEPGforSCADA,communicationsandcathodic
protectionofgaspipeline.
Fig.4.LowpowerTEPGproduces2.5W
at3.3V
on
matchedload
madebyHi—ZTechnology,Inc.
photonL2“.hydrogenandotherinflammablegasleakL2“.
Shineta1.attheSynergyMaterialsResearchCenterofAIST,Japan,recentlyreportedapromisinghydrogen-selectivesensoroperatingatambienttemperature.The
sensor
consistedof
a
thermoelectricminfilmand
a
half
surfacepartofPtfilm.Whensensor
wasexposedtothe
gasmixtureofairandhydrogengas,theselectivecatalyticoxidationofhydrogenheatsupthesurfaceofPtfilm,andmenthermoelectricvoltagebuildsupalongthehotandcoldregion
ofthethermoelectricfilm.Such
a
sensor
is
expectedtobecapableofdetectingsmallconcentrationofhydrogenmoleculeswithhighsensitivity02….
Traditionalgassensorsarebecominglaggingtothe
requirmentsofmodemindustryduetotheirweaknessoflargesize,heavyweight,complexity,low
selectivityto
R氅Vl鲢WS
certain
gas(responsetomostinflamblegas),andslow
action.Furthermore.thesensitivity1argelydependson
operatingtemperature,whichnotonlydemandsextraheatelements,butalsoisapotentialoffire.whereas
thermoelectricgassensorownsmeritsofoperatingatroomtemperature,smallsize,highselectivityandquickresponse.1%mixtureofhydrogengasand
air
can
generateanoutputvoltageof2mVwitha
response
time
of50s.Fig.5givesthemeasuringpropertiesofvoltageas
afunctionofhydrogenconcentration.
>
姜
司
O100200300400500600
Time/s
Fig.5.Hydrogensensingpropertiestodifferenthydrogenconcentra—
tionsofameⅡnoelectricsensormadeinJapan.
D.T.S.GmbHcompanyexplored
a
microinfrared
sensor
rIRS.235)based
on
itsproductof235
thermopiles
aiming
at
detectionofactivelyinflaredradiation“.These
sensors
donotneed
afilterwindow.possessa
highre.
sponsibility,arenotinfluencedbyheatconductionand
heat
convectionofthe
surroundings,and
are
resistant
againsthighintensityofheat
radiation.They
canbeusedforcontactlesstemperaturemeasurementandmonitoring,presenceandmotiondetectors,electronicheatcostallo—
cators,IR.measurementequipmentandsoon.Fig.6showstheflexiblefoilIRsensorswithasizeof5.6mm×
3.1mm×0.08mm.andweightof19mg.
(vi)Waste
heatpowergeneration.
Inrecentyears.concerns
are
largelyarousedbythelargeconsumptionof
fossilfuelandenvironmentaldamagecausedbytheextraburningoffossilfuels.Ithasbeenrealizedthatinsitua—tionswherethesupplyofheatischeap
or
flee.ef!ficiency
oftheTEPGsystemisnotanoverridingconsideration.Theuseofwasteheatasanenergyso,。u。r、ce
increasesthe
commercialcompetitivenessofTEPGo‘“.Japanesegov.
ernmentcarriedout‘‘RecycleandResearch
on
Solid
Waste
FuelProgram”severalyearsago.aimingatgener-
atlngelectricPowerfromwasteheatthroughcogeneratlonofTEPGandgasturbinesystemL。J.In2003.DOEofUSAannouncedtosupportPPGIndustries(Inc.ofPittsburgh),
1)D.T.S.GmbH,Infrared—sensors.http://www.dts—generator.com/sen—txe.htm,2003
Ch『仃eseScienceBulletinV01.49
No.12
June2004
1215
R驻Vl程鞴器
Fig.6.Flexiblefoil(IRS一235F)IR
sensors
producedbyD.T.S.GmbH
company.
MichiganTechnologicalUniversity,andPaciticNorthwest
NationalLaboratorytoperformhigh..effciencythermoele..ctricenergyconversionmaterialsandtechnologytore—coverwasteenergyfromexhaustedgasandotherinfra—structureheatdischargedbyindustrialprocessingplants”.
f11Industrialwasteheat.Thegreatdevelopmentof
industrializationacceleratestheemittingofvastamountsofwasteheatfromfactories,industries,manufacturing
plantsand
powerutilities,such
as
chemicalplants,oil
refineries,paperricemills,sugarmills.Industrialwaste
heatisreleasedingases
or
liquidsmediaattemperaturef<
450K1thatistoolowfor
use
inconventionalpowergen—
eratingunits.TEPGofiers
an
alternative
ofelectricity
generationpoweredbylowtemperaturewasteheat,andatthesametimepartlysolvestheworldwideenergvcon.straint.Thereplacementofby—heatboilerandgasturbinebythermoelectricdevicesmakesitcapableoflargely
re—
ducingcapitalcost,increasingstability,savingenergYsource.andprotectingenvironmentL2“.Fig.7showsanexampleofTEPGusedinnaturalgasfieldtoproducepowerforcathodicprotectionofthewellandgasline“.
(2)Garbageincinerator.Thetreatmentoflarge
amountsoflivinggarbagegeneratedeverydayisaseriousproblemaroused
by
the
highlyextensionofcitiesand
greatlyincrementofpopulation.0rganiccombustiblema—terialscontainedingarbageareregardedasthesecond—classenergywhichownslargeamountsofheat.Forex—ample,burning200tonsgarbage
can
generate2000kW
electricity“.Generatingelectricityfromgarbagewillbringseriesofadvantages,includingexploitingofnewenergysource,loweringpowercost,andreducingairpollution.A
commonprototypeis
a
cogenerationofTEPGwithgar—
bageincineratorbyplacingthermoelectricmodulesonwallsofthefurnace’sfunnels.Thisconstructioncaneliminate
theby—heat
furnace,gas
turbine
andother
appendentpartsofsteamrecycle.
Bynow,moreandmoreattentionsare
focused
on
the
investigationofTEPGbasedon
lifegarbagebydeveloped
countries,such
as
USA,Japan,France,UK,Germany
and
Italy瞄….InFig.8anexampleofTEPGfacingtogarbageincineratorwasshownwithapowerdensityof100kW/m3.
Theannualeconomicalcostforgarbagetreatmentis
very
1argeinChina.Ifinvolvingthetransmissionand
disposalcost.itattainednearly30billionYuan.Inotherwords,250billionYuan
can
begotifthegarbagecanberationallyutilizedL2….In
ordertoattractmoreconcern
fromindustriesandfactories,theState
Departmentof
Chinaenactedseriesofpreferentialpolicytostimulatethe
R&Dofpowergenerationfromtheintegratedusingofgarbage.
Fig.7.ATEPGproducedpowerforcathodicprotectionofthewellandgasline,whichusedthetemperaturedifferencebetweenhotandcoldlegsofglycolnaturalgasdehydratorcycle.
f3)Wasteheatfromautomobile.Therecovering
ofheatfromexhaustgasesinautomobilesisatypicalap—plicationofelectricitygenerationusingTEPGAutomo—
bilesbringusadvantagessuchasefficiencyandconven—ience,atthesametimeresultintheenvironmentpollutionandgreatconsumptionoffuel.Theelectricalpowerusedinautomobilesisgeneratedusingpartoftheenergycon一
1)OfficeofIndustrialtechnologies,U.S.A.DOEselects32
new
projects
to
improveenergy
efficiencyinU.S.industry.http://www
oit.doe.gov/cfm/fullarticle.cfm/id=782,2003.
2)Hi—ZTechnology.Powerfromwasteheatingasproductionfield.http://www.hi—z.com/websitl4.htm,2003.
3)Electricfrom
garbage--Thebrightfutureofpowergenerationfromgarbage.http://www.china.com.cn/chinese/huanjing/247355.htm,2002.
1216
∞inese
ScienceBulletinV01.49No.12June
2004
Fig.8.TEPGproducedbytheJapaneseEnergyConservasionCenter,whichusedwasteheatasenergysourcetogenerateanelectricpowerdensityof100kW/m3.
veaedinto
a
drivingforcewith
an
alternator.Thecentral
problemoftheenergy
transformationisthatonly
part
of
theener£yflow
supplied
bythe
fuel
isconvened
into
brakepoweroutput.Theenergydissipatedislostbytransmissiontotheenvironmentthroughexhaustgas,coolingwater.1ubricationoilandradiation【3….Forin.stance.in
a
gasolineengine.about30%oftheprimary
gasolineenergyisdischargedaswasteheatintheexhaustgases.Ifapproximately6%ofthewasteheatcouldbe
converted
intoelectfical
power,thefuelconsumption
around10%wouldbepossibletobereduced“.Thisisthereason
whyTEPG
can
beprofitableinthe
automobile
industry.
JapanhasdevelopedasmalltyDeofTEPGusingtheexhaustgasheatfromautomobilestoproduceanelectricpowerof100W.andsave5%ofthegasolineconsump—tion【“J.USArecentlydeclareditsproductionofa1kWTEPGusedonadieseltruck【32’3。J.Fig.9istheMacktruckequippedwiththisTEPGrunningoutofChandler,Ari—zona.Thegeneratorlookslikethe仃uck’sverticalmuffier.whichitreplaces.ThisTEPGcanbeemployedasasub—stituteforthetruckenginealternator.Powertothedriveshaftincreasesbythreetofivehorsepower,whichin—
creases
fuel
efficiency
andreducesemissions.
f41Natural
source.
Solarradiation.temperaturedifference
between
air
andocean/groundareendless
naturalheatsource.Traditionalpowergeneratorsbasedonnaturalheatdemandheatengine,dynamotor,orsteamturbinetoact
as
impulsionengine.Withsuch
a
complex
structuretheapplicationofgeneratorhas
to
berestrained
merelytolargepower。generationconsideringtheeco_nomicalbenefit.Steven【。’1’‘7fromtheMississippiStateUniversityofUSAused
a
commerciallyavailableTEPG
鼗鲢V|瑟糕S
for
powergeneration
to
operate
betweentheairand
groundtemperatureswithadailyaverageelectricalenergyof100mWfFig.10).Advantagesofthissysteminvolvelongservicelife(0_一10years),noacousticemissions,low
visibility(halfair,halfground),significantnighttime
powerproductionandruggedness.Thisdesignisproposedtobecommonlyusedingaspipelineinstrumentation.spacecraftpower,weatherstationinstrumentation.envi.
ronmental
or
militarymonitoringandothers.Thecommon
heatsourcesincludecombustionofhydrocarbonfuels,
radioisotopematerials,wasteprocessheat,andsolaren—
ergy.
Fig.9.Macktruckequippedwith
a
1kWTEPGwithdriveshaftin
creasedby
3—5horsepower.
Fig.10.SchematicofGround—sourcethermoelectric
generator
(51Dispersedheat.Rowe”…attheSchoolofEngi—
neeringatCardiffUniversitymadeademonstrationofelectricitygenerationbyusinglowtemperaturewasteheat
With
theexperimentalset—up.heshowedthattheamount
ofheatcontainedinthewaterleftaftera
bathwas
suffi—
cienttoprovidethe
electricityneededtopower
a
color
1)VOzquez…J
Sanz—Bobi,M.A.,Palacios,R.eta1.,Stateofthe
art
of
thermoelectric
generatorsbasedonheatrecoveredfromtheexhaustgases
ofautomobiles.http://www.iit.upco.es/palacios/thermo/EWT02一Exhaust_gases.pdf.
2)Stevens,J.W.,Energyharvesting:Aground-sourcethermoelectricgenerator.http://www.darpa.mil/dso/trans/energy/briefings/18Steve.PDF,
2000.
ChineseScienceBulletinV01.49No.12June2004
1217
Recent developments of thermoelectric power
generation
作者:LUAN Weiling, Tu Shantung
作者单位:East China University of Science and Technology, School of
MechanicalEngineering, Shanghai 200237, China
刊名:
科学通报(英文版)
英文刊名:CHINESE SCIENCE BULLETIN
年,卷(期):2004,49(12)
被引用次数:5次
参考文献(45条)
1.Kyeo H-K.Khajetoorians, A. A.Shi, L Profiling the thermoelectric power of semiconductor junctions with nanometer resolution 2004
2.Hsu K F.Loo, S.Fuo, E Cubic AgPbmSbTe2+m: Bulk thermoelectric materials with high figure of merit 2004
3.Harman T C.Taylor, P. J.Walsh, M. P Quantum dot superlattice thermoelectric materials and devices 2002
4.Venkatasubramanian R.Siivola, E.Colpitts, T. B Thin-film thermoelectric devices with high room-temperature figures of merit 2001
5.Chung D.Hogan, T.Brazis, P CsBi4Te6: A high- performance thermoelectric material for low-temperature applications 2000
6.DiSalvo E J Thermoelectric cooling and power generation 1999
7.Tritt T M Thermoelectric materials: Holey and unholey semiconductors 1999
8.Nolas G S.Morelli D T.Tritt T M Skutterudites: A phonon-glass-electron crystal approach to advanced thermoelectric energy conversion applications 1999
9.Ni Q Y Recent development of power generation directly from solar heat 1996
10.He Y J.Chen, H.Chen, M. X Thermoelectric electricity generation-a new green energy technique 2000
11.Jiao Z K.Wang, Z. B Recent development of thermoelectric materials 2002
12.Tang X F.Chen.L.D.Goto.T Synthesis and thermoelectric properties of filled skutterudite compounds CeyFeχCo4-χSb12 by solid state reaction, J 2001
13.Rinehart G H Design characteristics and fabrication of radioisotope heat sources for space missions 2001
14.Ghamaty S.Bass J C.Elsner N B Quantum well thermoelectric devices and applications 2003
15.Nuwayhid R Y.Rowe,D.M.Min,G Low cost stove-top thermoelectric generator for regions with unreliable electricity supply 2003
16.Weinberg F J.Powe D M.Min G Novel high performance small-scale thermoelectric power generation employing regenerative combustion systems 2002
17.Schmidt M A Portable MEMS power sources 2003
18.Ryan M A.Fleurial, J. P Where there is heat, there is a way:thermal to electric power conversion using thermoelectric microconverters, Electrochemical Soc 2002
energy sources,Proceedings of 18th International Conference on Thermoelectrics,Baltimore (USA): Int 1999
20.Haruyama T Performance of Peltier elements as a cryogenic heat flux sensor at temperature down to 60 K 2001
21.Gulian A.Wood, K.Fritz, G X-ray/UV single photon detectors with isotropic Seebeck sensors, Nuclear Instruments and Methods in Physics Research Section A 2000
22.Matsumiya M.Shin W.Izu N Thermoelectric CO gas sensor using Au and Co3O4 thin film 2004
23.Qiu F.Matsumiya, M.Shin, W Investigation of thermoelectric hydrogen sensor based on SiGe film 2003
24.Schieferdecker J.Quad, R.Holzenkaimpfer, E Infrared thermopile sensors with high sensitivity and very low temperature coefficient 1995
25.Kyono T.Suzuki, R. O.Ono, K Conversion of unused heat energy to electricity by means of thermoelectric generation in condenser 2003
26.Sugimoto T Demand forecast of thermoelectric power generating system 2000(07)
27.Kolay P K.Singh D N Application of coal ash in fluidized thermal beds 2002
28.Bass J C.Kushch·A·S.Eisner, N·B Development of a self-powered pellet stove, the 19th International Conference on Thermoelectrics 2000
29.Power generation from garbage Chinese Environment Report (in Chinese), Dec. 27 2001
30.Rowe D M Thermoelectrics: An environmentally-friendly source of electrical power 1999
31.Shinohara K.Kobayashi M.Kushibiki K Application of thermoelectric generator for automobile 1999
32.Yodovard P The potential of waste heat thermoelectric power generation from diesel cycle and gas turbine cogeneration plants 2001
33.Masahide M.Michio·M.Masaru, O Thermoelectric generator utilizing automobile engine exhaust gas 2001
34.Stevens J W Heat transfer and thermoelectric design considerations for a ground-source thermoelectric generator, Proceedings of the 18th International Conference on Thermoelectrics Baltimore (USA): Int 1999
35.Chen G.Dresselhaus, M. S.Dresselhaus, C Recent developments in thermoelectric materials 2003
36.Slack G A CRC Handbook of Thermoelectrics 1995
37.Bhattacharya S.Ponnambalam V.Pope A L Effect of substitutional doping on the thermal conductivity of Ti-based half-Heusler compounds 2001
38.Tritt T M.Wilson M L.Johnson A L Potential of quasicrystals and quasicrystal approximants for new and improved thermoelectric materials 1997
39.Uchino H.Okamoto Y.Kawahara. T Study of the origin of the anomalously large thermoelectric power of Si/Ge superlattice thin film 2000
40.Beyer H.Nurnus, J.Bottner, H Thermoelectric properties of PbSr(Se,Te)-based low dimensional structures, Proceeding of IEEE International Symposium on Circuits and Systems 2001
Conference on Thermoelectrics 2001
42.Matsubara I.Funahashi R.Shikano M Cation substituted (Ca2CoO3)χCoO2 films and their thermoelectric properties 2002
43.Takahata K.Iguchi, Y.Tanaka, D Low thermal conductivity of the layered oxide (Na,Ca)Co2O4: Another example of a phonon glass and an electron crystal 2000
44.Hicks L D.Dresselhaus, M. S Effect of quantum-well structures on the thermoelectric figure of merit 1993
45.Wang M.Zhang, Y.Muhanned, M Synthesis and characterization of nano-engineered thermoelectric skutterudite via solution chemistry route 1999
相似文献(10条)
1.外文期刊LUAN Welling.TU Shantung Recent developments of thermoelectric power generation
One form of energy generation that is expected to be on the rise in the next several decades is thermoelectric power generation (TEPG) which converts heat directly to electricity. Compared with other methods, TEPG possesses the salient features of being compact, light-weighted, noiseless in operation, highly reliable, free of carbon dioxide emission and radioactive substances. Low current conversion efficiency and high cost, however, are some of the disadvantages. Use of TEPG is therefore justified to hightech applications associated with aerospace, military operation, tel-communication and navigation, instrumentation of unmanned vehicles monitored from remote locations. Moreover, TEPG does not contribute to the depletion of natural resource and pollution of the environment such as climate warming that has been a concern in recent times. This work is concerned with providing an overview of the state of the art of TEPG with emphases placed on assessing its current and potential application. Pointedout are the ways to
fabricate high performance thermoelectric material, a hurdle to overcome for the enhancement of TEPG device efficiency.
2.外文期刊Dughaish ZH.Lead telluride as a thermoelectric material for thermoelectric power
generation
The specialized applications of thermoelectric generators are very successful and have motivated a search for materials with an improved figure of merit Z, and also for materials which operate at elevated temperatures. Lead telluride, PbTe, is an intermediate thermoelectric power generator. Its maximum operating temperature is 900 K. PbTe has a high melting point, good chemical stability, low vapor pressure and good chemical strength in addition to high figure of merit Z. Recently, research in thermoelectricity aims to obtain new improved materials for autonomous sources of electrical power in specialized medical, terrestial and space applications and to obtain an unconventional energy source after the oil crises of 1974. Although the efficiency of thermoelectric generators is rather low, typically similar to 5%, the other advantages, such as compactness, silent, reliability, long life, and long period of operation without attention, led to a wide range of applications. PbTe thermoelectric generators have been widely used by the US army, in space crafts to provide onboard power, and in pacemakers batteries. The general physical properties of lead telluride and factors affecting the figure of merit have been reviewed. Various possibilities of improving the figure of merit of the material have been given, including effect of grain size on reducing the lattice thermal conductivity lambda(L). Comparison of some transport properties of lead telluride with other thermoelectric materials and procedures of preparing compacts with transport properties very close to the single crystal values from PbTe powder by cold and hot-pressing techniques are discussed. (C) 2002 Elsevier Science B.V. All rights reserved. [References: 75]
3.外文会议Caillat. T..Fleurial. J.-P..Institute of Electric and Electronic Engineer Zn-Sb alloys
for thermoelectric power generation
/spl beta/-Zn/sub 4/Sb/sub 3/ was identified as a new high performance p-type thermoelectric material (Caillat et al., 1996). A maximum dimensionless thermoelectric figure of merit ZT of about 1.3 was obtained on p-type /spl beta/-Zn/sub 4/Sb/sub 3/ samples at a temperature of about 400/spl deg/C. This is the highest figure of merit ever obtained at this temperature for a p-type thermoelectric material. The possibility of improving ZT values by forming Zn/sub 4-x/Cd/sub x/Sb/sub 3/ solid solutions was studied. Preliminary results obtained on alloys between Zn/sub 4/Sb/sub 3/ and Cd/sub 4/Sb/sub 3/ are presented and show that the lattice thermal conductivity can be reduced. As a result, a maximum ZT value of 1.4 at a temperature of about 250/spl deg/C was obtained for a sample with a composition Zn/sub 3.2/Cd/sub 0.8/Sb/sub 3/. Initial bonding and stability studies are presented and show that the integration of these materials into devices is possible. The efficiency of a thermoelectric generator using these new materials was calculated and the results show that significant improvements are possible compared to state-of-the-art thermoelectric materials. Some potential applications for these new thermoelectric materials are described.
4.外文会议Julio E. Rodriguez LSCO Ceramics as Possible Thermoelectric Material for Low Temperature
Applications
Temperature dependent Seebeck coefficient S(T), thermal conductivity κ(T) and electrical resistivity ρ(T) measurements on polycrystalline La_(1.85)Sr_(0.15)CuO_(4-δ)^s(LSCO) compounds grown by solid-state reaction method were carried out in the temperature range between 100 and 290K. The obtained samples were submitted to annealing processes of different duration in order to modify their oxygen stoichiometry. The Seebeck coefficient is positive over the measured temperature range and its magnitude increases with the annealing time up to approximately 150 μV/K. The electrical resistivity exhibits a metallic behavior, in all samples with ρ(T) values less than 1mΩ-cm. As the annealing time increases, the total thermal conductivity increases to values near 3 W/K-m. From S(T), κ(T) and ρ(T) data, the thermoelectric power factor (PF) and the dimensionless figure of merit (ZT) were determined. These parameters reach maximum values around 25 μW/K~2-cm and 0.18, respectively. The observed behavior in the transport properties become these compounds potential thermoelectric materials, which could be used in low temperature thermoelectric
applications.
5.外文会议Kajikawa. T..Institute of Electric and Electronic Engineer Status and future prospects on
the development of thermoelectric power generation systems utilizing combustion heat from municipal
solid waste
The characteristics of combustion heat from the municipal solid waste are fitted for a large-scale application of thermoelectric power generation potentially. The status and future prospects of thermoelectric power generation systems to recover electricity from this heat source in Japan are reviewed and discussed. Experimental results on three different types of small-scale (500 W class) thermoelectric power generation systems installed in the real municipal solid waste processing systems to demonstrate the technological feasibility and to extract the technological problems are briefly introduced. The conceptual designs of a small scale system for the next phase of the R&D program are presented. From the view point of large-scale realization the thermoelectric material and modules configurations required for this application are also discussed. A case study on the marginal cost estimation shows the cost reduction to be less than 0.4-0.5 Million Yen/kW in order to make a profit on this system.
6.外文会议Douglas T. Crane.Lon E. Bell DESIGN TO MAXIMIZE PERFORMANCE OF A THERMOELECTRIC POWER
GENERATOR WITH A DYNAMIC THERMAL POWER SOURCE
It is a difficult technical challenge to design thermoelectric power generation systems that work optimally over a broad dynamic range of thermal input power. Conventional systems are designed to work optimally for a nominal operating condition, while maintaining the ability to operate at off nominal and extreme operating conditions without damage to the system. For systems that operate in a narrow range of thermal power conditions, thermoelectric waste heat recovery system design is simplified. However, for applications that do have a wide range of operating conditions, designs typically exhibit overall average efficiencies that are reduced by approximately 20% or more compared to that achievable for the thermoelectric material operating at peak efficiency. Both cars and trucks consume significant fuel at low mass flow rates. Since the ultimate goal of waste heat recovery systems is to minimize fuel consumption, it is critical that the recovery system be designed to operate near peak efficiency over the range of mass flow rates that make a significant contribution to overall power recovery. Such performance capability is especially important in
city driving, and in hybrid vehicle applications.This paper describes a design concept that maximizes the performance for thermoelectric power generation systems in which the thermal power to be recovered is from a fluid stream (e. g. exhaust gas) subject to varying temperatures and a broad range of fuel flow rates. The device is constructed in several parts, with each part optimized
for a specific range of operating conditions. The thermoelectric system characteristics, inlet mass flow rates and fluid temperatures, and load and internal electrical resistances are monitored and generator operation is controlled to maximize performance. With this design, the system operates near optimal efficiency for a much wider rangeof operating conditions. Application of the design concept to an automobile is used to show the benefits to
7.外文期刊Douglas T. Crane.Lon E. Bell Design to Maximize Performance of a Thermoelectric Power
Generator With a Dynamic Thermal Power Source
It is a difficult technical challenge to design thermoelectric power generation systems that work optimally over a broad dynamic range of thermal input power. Conventional systems are designed to work optimally for a nominal operating condition, while maintaining the ability to operate at off nominal and extreme operating conditions without damage to the system. For systems that operate in a narrow range of thermal power conditions, thermoelectric waste heat recovery system design is simplified. However, for applications that do have a wide range of operating conditions, designs typically exhibit overall average efficiencies that are reduced by approximately 20% or more compared with that achievable for the thermoelectric material operating at peak efficiency. Both cars and trucks consume significant fuel at low mass flow rates. Since the ultimate goal of waste heat recovery systems is to minimize fuel consumption, it is critical that the recovery system be designed to operate near peak efficiency over the range of mass flow rates that make a significant contribution to overall power recovery. Such performance capability is especially important in
city driving, and in hybrid vehicle applications. This paper describes a design concept that maximizes the performance for thermoelectric power generation systems in which the thermal power to be recovered is from a fluid stream (e.g., exhaust gas) subject to varying temperatures and a broad range of exhaust flow rates. The device is constructed in several parts, with each part optimized for a specific range of operating conditions. The thermoelectric system characteristics, inlet mass flow rates and fluid temperatures, and load and internal electrical resistances are monitored and generator operation is controlled to maximize performance. With this design, the system operates near optimal efficiency for a much wider range of operating conditions. Application of the design concept to an automobile is used to show the benef
8.外文期刊K. M. SAQR.M. K. MANSOUR.M. N. MUSA THERMAL DESIGN OF AUTOMOBILE EXHAUST BASED
THERMOELECTRIC GENERATORS: OBJECTIVES AND CHALLENGES
The potential for thermoelectric power generation (via waste heat recovery onboard automobiles) to displace alternators and/or provide additional charging to a vehicle battery pack has increased with recent advances in thermoelectric material processing. In gasoline fueled vehicles (GFVs), about 40% of fuel energy is wasted in exhaust heat, while a smaller amount of energy (30%) is ejected through the engine coolant. Therefore, exhaust-based thermoelectric generators (ETEG) have been a focus for GFV applications since the late 1980s. The conversion efficiency of modern thermoelectric materials has increased more than three-fold in the last two decades; however, disputes as to the thermal design of ETEG systems has kept their overall efficiency at limited and insufficient values. There are many challenges in the thermal design of ETEG systems, such as increasing the efficiency of the heat exchangers (hot box and cold plate), maintaining a sufficient temperature difference across the thermoelectric modules during different operating conditions, and reducing thermal losses through the system as a whole. This paper focuses on a review of the main aspects of thermal design of ETEG systems through various investigations performed over the past twenty years. This paper is organized as follows: first, the construction of a typical ETEG is described. The heat balance and efficiency of ETEG are then discussed. Then, the third section of this paper emphasizes the main objectives and challenges for designing efficient ETEG systems. Finally, a review of ETEG research activities over the last twenty years is presented to focus on methods used by the research community to address such challenges.
9.外文会议J. B. Posthill.J. C. Caylor.P. D. Crocco.T. S. Colpitts.R. Venkatasubramanian High-
Temperature PbTe Thin Films for Use in Cascade Thermoelectric Power Generation
PbTe-based thin films were deposited by thermal evaporation at temperatures ranging from ambient temperature to 430 ℃ on
thermoelectric material for a mid-temperature stage in a cascade power generation module. Pure PbTe, PbSe, and multilayer PbTe/PbSe films were investigated. All films deposited on different vicinal GaAs (100) substrates were found to be polycrystalline when deposited at 250 ℃ or lower. A subtle effect of substrate orientation and multilayer periodicity appears to contribute to the more randomly oriented polycrystallinity, which also lowers the thermal conductivity. These results are compared with PbTe epitaxial
results on BaF_2 (111).
10.外文期刊AARON D. LALONDE.PETER D. MORAN Synthesis and Characterization of p-Type
Pb_(0.5)Sn_(0.5)Te Thermoelectric Power Generation Elements by Mechanical Alloying
A mechanical alloying (MA) process to transform elemental powders into solid Pb_(0.5)Sn_(0.5)Te with thermoelectric functionality comparable to melt-alloyed material is described. The room-temperature doping level and mobility as well as temperature-dependent electrical conductivity, Seebeck coefficient, and thermal conductivity are reported. Estimated values of lattice thermal conductivity (0.7 W m~(-1) K~(-1)) are lower than some reports of functional melt-alloyed PbSnTe-based material, providing evidence that MA can engender the combination of properties resulting in highly functional thermoelectric material. Though doping level and Sn composition have not been optimized, this material exhibits a ZT value > 0.5 at 550 K.
引证文献(5条)
1.王国文.王秀峰.于成龙.江红涛.李金换.陈思涛梯度热电材料的研究进展[期刊论文]-材料导报 2007(7)
2.ZHOU Min.LI JingFeng.WANG Heng Fabrication and property of high-performance Ag-Pb-Sb-Te system semiconducting thermoelectric materials[期刊论文]-科学通报(英文版) 2007(7)
3.张建松热电薄膜氢气传感器中催化剂的研究[学位论文]硕士 2007
4.栾伟玲.毛顺杰.涂善东.高濂.郭景坤锶掺杂铅酸钡陶瓷的热电性能[期刊论文]-硅酸盐学报 2006(2)
5.毛顺杰Ba<,1-x>Sr<,x>PbO<,3>热电氢气传感器的研究[学位论文]硕士 2004
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