Recent developments of thermoelectric power generation

鞣鼹甏l醛瓣黪

C打ineseScienceBulletin2004V01.49No.121212—1219

Recentdevelopmentsof

thermoelectricpower

generation

LUAN

Weiling&TUShantung

East

ChinaUniversityofScienceandTechnology,Schoolof

Mechanical

Engineering,Shanghai200237,ChinaCorrespondenceshouldbeaddressedto

Luan

Weiling(e-mail:luan@

ecust.edu.cn)

Abstract

0neformofenergygenerationthatisexpected

tobe

on

therise

inthenextseveraldecadesisthermoelectric

power

generation(TEPG)whichconvertsheatdirectlyto

electricity.Comparedwithothermethods,TEPGpossessesthesalientfeaturesofbeingcompact,light-weighted,noiselessinoperation,highlyreliable,freeofcarbondioxide

emissionandradioactivesubstances.Lowcurrentconversionefnciency

andhighcost.however,

are

some

ofthe

disadvanta2es.UseofTEPGisthereforejustifiedtohightechapplicationsassociatedwithaerospace,militaryoperation,

tel.communication

and

navigation。

instrumentationofunmannedvehiclesmonitoredfromremotelocations.More-over.TEPGdoesnotcontHbutetothedepletionofnatural

resource

andpollutionoftheenvironmentsuch

as

climate

warmingthathasbeenaconcerninrecenttimes.ThisworkisconcernedwithprovidinganoverviewofthestateoftheartofTEPGwithemphasesplacedonassessingitscurrentandpotentialapplication.Pointedoutarethewaystofabri-cate

high

performancethermoelectricmaterial。ahurdleto

overcomefortheenhancementofTEPGdeviceemciency.

Keywords:thermoelectricpowergeneration,thermoelectricmaterial,

electricpower,thermoelectricsensor.

Thesearchfor

green,compact.10ng-lasting,

low..maintenancecommercialmethodsofgeneratingelec..trical

powerhasincreasedin

priority

as

thepublic

be—

comesmoreawareofenergyconservationandenviron—

mentprotection.Fuelcellsandotheralternativesarecur—

rentlybeinginvestigated.They.however,encounter

diffi—

culties

inpracticalapplication.Comparativelyspeaking,

TEPGhasbeenrecognizedasoneofthemajorenergYconversion

technologies,mainlybecauseoftheadvan—

tagesmentionedearlierwhichincludecompactsize,lightweight.noiselessnessandnoemission.TheUS0fficeofSpace&DefensePowerSystemsregardsTEPGasaprovenmethodforenergygenerationintermsofsafety,reliabilityandmaintainabilitv.Itisalsocapableofpro—

ducingeitherheator

electricityforlongperiodsoftimemeasurableindecades

under

hazardnessconditions

en—

counteredin

outer

space“.Therecentrecognitionwas

arisenthatTEPGdevicesarealsocost—effectiveifenvi—

ronmentistakenintoaccount.Thismakesthemethod

attractiveforthegenerationofelectricityinadditiontoitssuperiorfeaturesforapplicationinthehigh—techfieldsin—volvingspecializedmedicine.spaceandmilitaryuselilJ.ResearchanddevelopmentofTEPGhasbeenrecog—

nizedinmanydevelopedcountriesas10ngtomid—termscientificprograms.USAaimsprincipallyatitsapplica—tioninmilitary.spaceandhigh—techareas.TheJapanesegovernmentisfundingTEPGresearchinretrievingwaste

heat

emitted

from

automobiles,factoriesandsimilar

sources.The

EuropeanUnionfocusesattention

onlow.powergenerationandsensors.Chinamakesachieve.mentsoncoolingtheoryandtheproductionofthermo.

electricsemiconductorsalthoughwithlessemphasesonpowergenerationforthepresent.Thoughseveraloversea

companiesbuiltplantsinShanghai.Hangzhouandother

cities,theexplorationofthistechnologyandproductare

stilllackingo’1“.1

Mechanism

ofthermoelectricpowergeneration

Conversionofheatdirectlyintoelectricityisnot

newprinciple.Itwasdiscoveredin1822byaGerman

scientist,ThomasSeebeck.Heobservedthatan

electric

voltage

is

generated

when

twodissimilar,electrically

conductive

materials(iron

and

copper)areioinedina

closedcircuitandthetwo1unctionsarekeptatdifierenttemperatures.Suchpairsof{unctionsarecalledthermo.

electriccouples,andthephenomenonobservediscalledSeebeckeffect.

TheschematicofTEPG

isillustratedinFig.1.A

typicaldeviceiscomposedoftwoelectricallyconducting

Fig.1.SchematicdiagramofmulticoupleThermoelectricGeneration

Modules.

1)U.S.DepartmentofEnergy.AdvancedRadioisotopePowerSystems,http://nuclear.gov/space/arpsfact.pdf,20021212

∞inese

ScienceBulletinV01.49No.12June

2004

materials:onecalledN—typeandtheotherP—type.N—typematerialisdopedsothatitwillhaveanexcessofelectrons(moreelectrons

thanneededtocompleteaperfectmo—

lecularlatticestructure)andP—typematerialisdopedsothatitwillhaveadeficiencyofelectronsffewerelectronsthannecessarytocompleteaperfectlatticestructure).TheextraelectronsintheN—materialandtheholesresultingfromtheP—materialarethechargecarriers.Thesetwokindsofmaterials

are

connectedelectricallyinseriesby

highlyconductingmetalstripsandsandwichedbetweenthermallyconductingbutelectricallyinsulatingplates.Astheheatmovesfromthehottothecoldplate,thechargecarriersarecarriedwimtheheat.Heatalsoaffectschargecarriermovementinthereturnpathftypicallycopperwire).Becauseelectronsflowin

directionoppositeto

thatofhole.thecurrentgeneratingpotentialsinthepelletsdonotopposeoneanother,butareseries—adding.Theheat

movementinsemiconductormaterials

can

carryfarmore

chargecarriersthanthatofthereturnpathofacircuit.

Therefore.asignificantpotentialdifference(i.e.Seebeckvoltage)isgenerated.BylinkingtogetheralargenumberofthermoelectricPandNcouples,asizeablevoltagecanbegenerated.CommerciallyavailableTEPGcontainsl8

—128

couples.Thepoweroutputdepends

on

thermoelec—

tricmaterial’s

properties

and

the

temperature

gradient

betweencoldandhotends.

InTEPGelectricalchargecarriers(electronsorholes)

insteadoflatticearetheenergytransportmedia.Thereisno

needofmechanicalcomponentsorhazardousworkingfluidsduringthewholeprocess.Therefore,TEPGoffers

severaldistinct

advantages

over

other

technologiesin—

volving

no

movingparts

or

bulkfuids,lowmaintenance,

lightweight,novibration,noopticandsonicsignal,andflexibilityonheatsource.2

ApplicationsofthermoelectricpowergenerationThe

firstTEPGunitwasbuiltintheformerSovietUnionin

1942with

an

efficiency

of

1.5%一2%.In

the

l960s.theresearchinthisarea

wasintensifiedand

series

of

thermoelectric

devices

weremade

successfullyand

appliedinmilitarymissionsinvolvingremotetel_。com。。municationandnavigation.Duetothemorerecentcon—

cemofenergyandenvironmentcrisis,addedvaluewasgiventotheuseofTEPG

(i)Exploration

ofspace.TEPGhasprovided

continuouspowersafelyandreliablyoverthepastthreedecadesinregionsofspacewheretheuseofsolarpower

isnotfeasible.TheUSDepartmentofEnergy(DOE)hasusedTEPGforspaceformanyyearsLl“.TheApollo(tothemoon),Viking(toMars),Pioneer,Voyager,Ulysses,Galileo.andCassini(outerSolarSystem)missionsallusedTEPGs.TheTEPGsforthePioneer10spacecrafthaveoperatedflawlesslyfor30yearsandcontinuetopowerthe

spacecraft

as

ittravelsbeyond

Pluto.During

黢鹾Vl鼹暇翁

lastthreedecades,theUnitedStateshaslaunched25mis—sionsinvolving44TEPGs。whileTEPGshavenever

been

the

cause

of

spacecraftaccident.

TEPGdevicessupplyhundredsofwattsofelectrical

powerforspacecraftbydirectconversionoftheheatgen—eratedbythenaturaldecayofradioisotopematerials.SuchTEPG

is

thereforecalledRadioisotope

Thermoelec:tric

Generator(RTGl.RTGconsistsoftwomajorelements:aheatsourcethatcontainsdecaymaterials(Plutonium一238)

and

set

ofsolid—statethermocouples.Fig.2illustrated

thestructureofRTGanditsGeneralPurposeHeatSourcemodulesusedonspacecraft.

Fig.2.RadioisotopeThermoelectricGenerator(upper)andGeneral

PurposeHeatSourcemodules(10wer).

Nowhuman

being’sexploration

is

heading

to

heliopause.theboundarywheretheSun’sinfluenceendsandthedarkrecessesofinterstellarspacebegin.Togetabove

the

Sun,Ulysses

has

to

fly

aroundJupiterand

slingshotoutoftheplaneoftheplanets.NearJupiter,theSun’sraysare25timesweakerthanthoseneartheEarth.SolarpanelslargeenoughtocatchthisweakenergYwouldhaveweighedl200pounds.doublingtheweightofthespacecraftandmakingittooheavyforboosterrocketsfromtheshuttle.Instead,Ulysseswasequippedwithan

I汀G

weighingonly124pounds.Iteasilypowersallthe

probe’sonboardsystems,includingnavigation,communi—cationandscientificinstruments¨.

TheDOEandNASA

are

initiatingthedevelopment

of

newgenerationofpower

system

thatcould

be

usedfor

variety

ofmissions.ThenewRTGcalled

Multi—MissionRadioisotopeThermoelectricGeneratorfMMRTG),willbedesignedtooperateon

planetary

11

u.s.OfficeofSpace&DefensePowerSystems,Radioisotopepowersystems.http://nuclear.gov/space/gphs.html,2003

ChineseScienceBuliet/n

V01.49

No.12

June

2004

1213

Fig.3.

5000

WTEPGforSCADA,communicationsandcathodic

protectionofgaspipeline.

Fig.4.LowpowerTEPGproduces2.5W

at3.3V

on

matchedload

madebyHi—ZTechnology,Inc.

photonL2“.hydrogenandotherinflammablegasleakL2“.

Shineta1.attheSynergyMaterialsResearchCenterofAIST,Japan,recentlyreportedapromisinghydrogen-selectivesensoroperatingatambienttemperature.The

sensor

consistedof

thermoelectricminfilmand

half

surfacepartofPtfilm.Whensensor

wasexposedtothe

gasmixtureofairandhydrogengas,theselectivecatalyticoxidationofhydrogenheatsupthesurfaceofPtfilm,andmenthermoelectricvoltagebuildsupalongthehotandcoldregion

ofthethermoelectricfilm.Such

sensor

is

expectedtobecapableofdetectingsmallconcentrationofhydrogenmoleculeswithhighsensitivity02….

Traditionalgassensorsarebecominglaggingtothe

requirmentsofmodemindustryduetotheirweaknessoflargesize,heavyweight,complexity,low

selectivityto

R氅Vl鲢WS

certain

gas(responsetomostinflamblegas),andslow

action.Furthermore.thesensitivity1argelydependson

operatingtemperature,whichnotonlydemandsextraheatelements,butalsoisapotentialoffire.whereas

thermoelectricgassensorownsmeritsofoperatingatroomtemperature,smallsize,highselectivityandquickresponse.1%mixtureofhydrogengasand

air

can

generateanoutputvoltageof2mVwitha

response

time

of50s.Fig.5givesthemeasuringpropertiesofvoltageas

afunctionofhydrogenconcentration.

O100200300400500600

Time/s

Fig.5.Hydrogensensingpropertiestodifferenthydrogenconcentra—

tionsofameⅡnoelectricsensormadeinJapan.

D.T.S.GmbHcompanyexplored

microinfrared

sensor

rIRS.235)based

on

itsproductof235

thermopiles

aiming

at

detectionofactivelyinflaredradiation“.These

sensors

donotneed

afilterwindow.possessa

highre.

sponsibility,arenotinfluencedbyheatconductionand

heat

convectionofthe

surroundings,and

are

resistant

againsthighintensityofheat

radiation.They

canbeusedforcontactlesstemperaturemeasurementandmonitoring,presenceandmotiondetectors,electronicheatcostallo—

cators,IR.measurementequipmentandsoon.Fig.6showstheflexiblefoilIRsensorswithasizeof5.6mm×

3.1mm×0.08mm.andweightof19mg.

(vi)Waste

heatpowergeneration.

Inrecentyears.concerns

are

largelyarousedbythelargeconsumptionof

fossilfuelandenvironmentaldamagecausedbytheextraburningoffossilfuels.Ithasbeenrealizedthatinsitua—tionswherethesupplyofheatischeap

or

flee.ef!ficiency

oftheTEPGsystemisnotanoverridingconsideration.Theuseofwasteheatasanenergyso,。u。r、ce

increasesthe

commercialcompetitivenessofTEPGo‘“.Japanesegov.

ernmentcarriedout‘‘RecycleandResearch

on

Solid

Waste

FuelProgram”severalyearsago.aimingatgener-

atlngelectricPowerfromwasteheatthroughcogeneratlonofTEPGandgasturbinesystemL。J.In2003.DOEofUSAannouncedtosupportPPGIndustries(Inc.ofPittsburgh),

1)D.T.S.GmbH,Infrared—sensors.http://www.dts—generator.com/sen—txe.htm,2003

Ch『仃eseScienceBulletinV01.49

No.12

June2004

1215

R驻Vl程鞴器

Fig.6.Flexiblefoil(IRS一235F)IR

sensors

producedbyD.T.S.GmbH

company.

MichiganTechnologicalUniversity,andPaciticNorthwest

NationalLaboratorytoperformhigh..effciencythermoele..ctricenergyconversionmaterialsandtechnologytore—coverwasteenergyfromexhaustedgasandotherinfra—structureheatdischargedbyindustrialprocessingplants”.

f11Industrialwasteheat.Thegreatdevelopmentof

industrializationacceleratestheemittingofvastamountsofwasteheatfromfactories,industries,manufacturing

plantsand

powerutilities,such

as

chemicalplants,oil

refineries,paperricemills,sugarmills.Industrialwaste

heatisreleasedingases

or

liquidsmediaattemperaturef<

450K1thatistoolowfor

use

inconventionalpowergen—

eratingunits.TEPGofiers

an

alternative

ofelectricity

generationpoweredbylowtemperaturewasteheat,andatthesametimepartlysolvestheworldwideenergvcon.straint.Thereplacementofby—heatboilerandgasturbinebythermoelectricdevicesmakesitcapableoflargely

re—

ducingcapitalcost,increasingstability,savingenergYsource.andprotectingenvironmentL2“.Fig.7showsanexampleofTEPGusedinnaturalgasfieldtoproducepowerforcathodicprotectionofthewellandgasline“.

(2)Garbageincinerator.Thetreatmentoflarge

amountsoflivinggarbagegeneratedeverydayisaseriousproblemaroused

by

the

highlyextensionofcitiesand

greatlyincrementofpopulation.0rganiccombustiblema—terialscontainedingarbageareregardedasthesecond—classenergywhichownslargeamountsofheat.Forex—ample,burning200tonsgarbage

can

generate2000kW

electricity“.Generatingelectricityfromgarbagewillbringseriesofadvantages,includingexploitingofnewenergysource,loweringpowercost,andreducingairpollution.A

commonprototypeis

cogenerationofTEPGwithgar—

bageincineratorbyplacingthermoelectricmodulesonwallsofthefurnace’sfunnels.Thisconstructioncaneliminate

theby—heat

furnace,gas

turbine

andother

appendentpartsofsteamrecycle.

Bynow,moreandmoreattentionsare

focused

on

the

investigationofTEPGbasedon

lifegarbagebydeveloped

countries,such

as

USA,Japan,France,UK,Germany

and

Italy瞄….InFig.8anexampleofTEPGfacingtogarbageincineratorwasshownwithapowerdensityof100kW/m3.

Theannualeconomicalcostforgarbagetreatmentis

very

1argeinChina.Ifinvolvingthetransmissionand

disposalcost.itattainednearly30billionYuan.Inotherwords,250billionYuan

can

begotifthegarbagecanberationallyutilizedL2….In

ordertoattractmoreconcern

fromindustriesandfactories,theState

Departmentof

Chinaenactedseriesofpreferentialpolicytostimulatethe

R&Dofpowergenerationfromtheintegratedusingofgarbage.

Fig.7.ATEPGproducedpowerforcathodicprotectionofthewellandgasline,whichusedthetemperaturedifferencebetweenhotandcoldlegsofglycolnaturalgasdehydratorcycle.

f3)Wasteheatfromautomobile.Therecovering

ofheatfromexhaustgasesinautomobilesisatypicalap—plicationofelectricitygenerationusingTEPGAutomo—

bilesbringusadvantagessuchasefficiencyandconven—ience,atthesametimeresultintheenvironmentpollutionandgreatconsumptionoffuel.Theelectricalpowerusedinautomobilesisgeneratedusingpartoftheenergycon一

1)OfficeofIndustrialtechnologies,U.S.A.DOEselects32

new

projects

to

improveenergy

efficiencyinU.S.industry.http://www

oit.doe.gov/cfm/fullarticle.cfm/id=782,2003.

2)Hi—ZTechnology.Powerfromwasteheatingasproductionfield.http://www.hi—z.com/websitl4.htm,2003.

3)Electricfrom

garbage--Thebrightfutureofpowergenerationfromgarbage.http://www.china.com.cn/chinese/huanjing/247355.htm,2002.

1216

∞inese

ScienceBulletinV01.49No.12June

2004

Fig.8.TEPGproducedbytheJapaneseEnergyConservasionCenter,whichusedwasteheatasenergysourcetogenerateanelectricpowerdensityof100kW/m3.

veaedinto

drivingforcewith

an

alternator.Thecentral

problemoftheenergy

transformationisthatonly

part

of

theener£yflow

supplied

bythe

fuel

isconvened

into

brakepoweroutput.Theenergydissipatedislostbytransmissiontotheenvironmentthroughexhaustgas,coolingwater.1ubricationoilandradiation【3….Forin.stance.in

gasolineengine.about30%oftheprimary

gasolineenergyisdischargedaswasteheatintheexhaustgases.Ifapproximately6%ofthewasteheatcouldbe

converted

intoelectfical

power,thefuelconsumption

around10%wouldbepossibletobereduced“.Thisisthereason

whyTEPG

can

beprofitableinthe

automobile

industry.

JapanhasdevelopedasmalltyDeofTEPGusingtheexhaustgasheatfromautomobilestoproduceanelectricpowerof100W.andsave5%ofthegasolineconsump—tion【“J.USArecentlydeclareditsproductionofa1kWTEPGusedonadieseltruck【32’3。J.Fig.9istheMacktruckequippedwiththisTEPGrunningoutofChandler,Ari—zona.Thegeneratorlookslikethe仃uck’sverticalmuffier.whichitreplaces.ThisTEPGcanbeemployedasasub—stituteforthetruckenginealternator.Powertothedriveshaftincreasesbythreetofivehorsepower,whichin—

creases

fuel

efficiency

andreducesemissions.

f41Natural

source.

Solarradiation.temperaturedifference

between

air

andocean/groundareendless

naturalheatsource.Traditionalpowergeneratorsbasedonnaturalheatdemandheatengine,dynamotor,orsteamturbinetoact

as

impulsionengine.Withsuch

complex

structuretheapplicationofgeneratorhas

to

berestrained

merelytolargepower。generationconsideringtheeco_nomicalbenefit.Steven【。’1’‘7fromtheMississippiStateUniversityofUSAused

commerciallyavailableTEPG

鼗鲢V|瑟糕S

for

powergeneration

to

operate

betweentheairand

groundtemperatureswithadailyaverageelectricalenergyof100mWfFig.10).Advantagesofthissysteminvolvelongservicelife(0_一10years),noacousticemissions,low

visibility(halfair,halfground),significantnighttime

powerproductionandruggedness.Thisdesignisproposedtobecommonlyusedingaspipelineinstrumentation.spacecraftpower,weatherstationinstrumentation.envi.

ronmental

or

militarymonitoringandothers.Thecommon

heatsourcesincludecombustionofhydrocarbonfuels,

radioisotopematerials,wasteprocessheat,andsolaren—

ergy.

Fig.9.Macktruckequippedwith

1kWTEPGwithdriveshaftin

creasedby

3—5horsepower.

Fig.10.SchematicofGround—sourcethermoelectric

generator

(51Dispersedheat.Rowe”…attheSchoolofEngi—

neeringatCardiffUniversitymadeademonstrationofelectricitygenerationbyusinglowtemperaturewasteheat

With

theexperimentalset—up.heshowedthattheamount

ofheatcontainedinthewaterleftaftera

bathwas

suffi—

cienttoprovidethe

electricityneededtopower

color

1)VOzquez…J

Sanz—Bobi,M.A.,Palacios,R.eta1.,Stateofthe

art

of

thermoelectric

generatorsbasedonheatrecoveredfromtheexhaustgases

ofautomobiles.http://www.iit.upco.es/palacios/thermo/EWT02一Exhaust_gases.pdf.

2)Stevens,J.W.,Energyharvesting:Aground-sourcethermoelectricgenerator.http://www.darpa.mil/dso/trans/energy/briefings/18Steve.PDF,

2000.

ChineseScienceBulletinV01.49No.12June2004

1217

Recent developments of thermoelectric power

generation

作者:LUAN Weiling, Tu Shantung

作者单位:East China University of Science and Technology, School of

MechanicalEngineering, Shanghai 200237, China

刊名:

科学通报(英文版)

英文刊名:CHINESE SCIENCE BULLETIN

年,卷(期):2004,49(12)

被引用次数:5次

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相似文献(10条)

1.外文期刊LUAN Welling.TU Shantung Recent developments of thermoelectric power generation

One form of energy generation that is expected to be on the rise in the next several decades is thermoelectric power generation (TEPG) which converts heat directly to electricity. Compared with other methods, TEPG possesses the salient features of being compact, light-weighted, noiseless in operation, highly reliable, free of carbon dioxide emission and radioactive substances. Low current conversion efficiency and high cost, however, are some of the disadvantages. Use of TEPG is therefore justified to hightech applications associated with aerospace, military operation, tel-communication and navigation, instrumentation of unmanned vehicles monitored from remote locations. Moreover, TEPG does not contribute to the depletion of natural resource and pollution of the environment such as climate warming that has been a concern in recent times. This work is concerned with providing an overview of the state of the art of TEPG with emphases placed on assessing its current and potential application. Pointedout are the ways to

fabricate high performance thermoelectric material, a hurdle to overcome for the enhancement of TEPG device efficiency.

2.外文期刊Dughaish ZH.Lead telluride as a thermoelectric material for thermoelectric power

generation

The specialized applications of thermoelectric generators are very successful and have motivated a search for materials with an improved figure of merit Z, and also for materials which operate at elevated temperatures. Lead telluride, PbTe, is an intermediate thermoelectric power generator. Its maximum operating temperature is 900 K. PbTe has a high melting point, good chemical stability, low vapor pressure and good chemical strength in addition to high figure of merit Z. Recently, research in thermoelectricity aims to obtain new improved materials for autonomous sources of electrical power in specialized medical, terrestial and space applications and to obtain an unconventional energy source after the oil crises of 1974. Although the efficiency of thermoelectric generators is rather low, typically similar to 5%, the other advantages, such as compactness, silent, reliability, long life, and long period of operation without attention, led to a wide range of applications. PbTe thermoelectric generators have been widely used by the US army, in space crafts to provide onboard power, and in pacemakers batteries. The general physical properties of lead telluride and factors affecting the figure of merit have been reviewed. Various possibilities of improving the figure of merit of the material have been given, including effect of grain size on reducing the lattice thermal conductivity lambda(L). Comparison of some transport properties of lead telluride with other thermoelectric materials and procedures of preparing compacts with transport properties very close to the single crystal values from PbTe powder by cold and hot-pressing techniques are discussed. (C) 2002 Elsevier Science B.V. All rights reserved. [References: 75]

3.外文会议Caillat. T..Fleurial. J.-P..Institute of Electric and Electronic Engineer Zn-Sb alloys

for thermoelectric power generation

/spl beta/-Zn/sub 4/Sb/sub 3/ was identified as a new high performance p-type thermoelectric material (Caillat et al., 1996). A maximum dimensionless thermoelectric figure of merit ZT of about 1.3 was obtained on p-type /spl beta/-Zn/sub 4/Sb/sub 3/ samples at a temperature of about 400/spl deg/C. This is the highest figure of merit ever obtained at this temperature for a p-type thermoelectric material. The possibility of improving ZT values by forming Zn/sub 4-x/Cd/sub x/Sb/sub 3/ solid solutions was studied. Preliminary results obtained on alloys between Zn/sub 4/Sb/sub 3/ and Cd/sub 4/Sb/sub 3/ are presented and show that the lattice thermal conductivity can be reduced. As a result, a maximum ZT value of 1.4 at a temperature of about 250/spl deg/C was obtained for a sample with a composition Zn/sub 3.2/Cd/sub 0.8/Sb/sub 3/. Initial bonding and stability studies are presented and show that the integration of these materials into devices is possible. The efficiency of a thermoelectric generator using these new materials was calculated and the results show that significant improvements are possible compared to state-of-the-art thermoelectric materials. Some potential applications for these new thermoelectric materials are described.

4.外文会议Julio E. Rodriguez LSCO Ceramics as Possible Thermoelectric Material for Low Temperature

Applications

Temperature dependent Seebeck coefficient S(T), thermal conductivity κ(T) and electrical resistivity ρ(T) measurements on polycrystalline La_(1.85)Sr_(0.15)CuO_(4-δ)^s(LSCO) compounds grown by solid-state reaction method were carried out in the temperature range between 100 and 290K. The obtained samples were submitted to annealing processes of different duration in order to modify their oxygen stoichiometry. The Seebeck coefficient is positive over the measured temperature range and its magnitude increases with the annealing time up to approximately 150 μV/K. The electrical resistivity exhibits a metallic behavior, in all samples with ρ(T) values less than 1mΩ-cm. As the annealing time increases, the total thermal conductivity increases to values near 3 W/K-m. From S(T), κ(T) and ρ(T) data, the thermoelectric power factor (PF) and the dimensionless figure of merit (ZT) were determined. These parameters reach maximum values around 25 μW/K~2-cm and 0.18, respectively. The observed behavior in the transport properties become these compounds potential thermoelectric materials, which could be used in low temperature thermoelectric

applications.

5.外文会议Kajikawa. T..Institute of Electric and Electronic Engineer Status and future prospects on

the development of thermoelectric power generation systems utilizing combustion heat from municipal

solid waste

The characteristics of combustion heat from the municipal solid waste are fitted for a large-scale application of thermoelectric power generation potentially. The status and future prospects of thermoelectric power generation systems to recover electricity from this heat source in Japan are reviewed and discussed. Experimental results on three different types of small-scale (500 W class) thermoelectric power generation systems installed in the real municipal solid waste processing systems to demonstrate the technological feasibility and to extract the technological problems are briefly introduced. The conceptual designs of a small scale system for the next phase of the R&D program are presented. From the view point of large-scale realization the thermoelectric material and modules configurations required for this application are also discussed. A case study on the marginal cost estimation shows the cost reduction to be less than 0.4-0.5 Million Yen/kW in order to make a profit on this system.

6.外文会议Douglas T. Crane.Lon E. Bell DESIGN TO MAXIMIZE PERFORMANCE OF A THERMOELECTRIC POWER

GENERATOR WITH A DYNAMIC THERMAL POWER SOURCE

It is a difficult technical challenge to design thermoelectric power generation systems that work optimally over a broad dynamic range of thermal input power. Conventional systems are designed to work optimally for a nominal operating condition, while maintaining the ability to operate at off nominal and extreme operating conditions without damage to the system. For systems that operate in a narrow range of thermal power conditions, thermoelectric waste heat recovery system design is simplified. However, for applications that do have a wide range of operating conditions, designs typically exhibit overall average efficiencies that are reduced by approximately 20% or more compared to that achievable for the thermoelectric material operating at peak efficiency. Both cars and trucks consume significant fuel at low mass flow rates. Since the ultimate goal of waste heat recovery systems is to minimize fuel consumption, it is critical that the recovery system be designed to operate near peak efficiency over the range of mass flow rates that make a significant contribution to overall power recovery. Such performance capability is especially important in

city driving, and in hybrid vehicle applications.This paper describes a design concept that maximizes the performance for thermoelectric power generation systems in which the thermal power to be recovered is from a fluid stream (e. g. exhaust gas) subject to varying temperatures and a broad range of fuel flow rates. The device is constructed in several parts, with each part optimized

for a specific range of operating conditions. The thermoelectric system characteristics, inlet mass flow rates and fluid temperatures, and load and internal electrical resistances are monitored and generator operation is controlled to maximize performance. With this design, the system operates near optimal efficiency for a much wider rangeof operating conditions. Application of the design concept to an automobile is used to show the benefits to

7.外文期刊Douglas T. Crane.Lon E. Bell Design to Maximize Performance of a Thermoelectric Power

Generator With a Dynamic Thermal Power Source

It is a difficult technical challenge to design thermoelectric power generation systems that work optimally over a broad dynamic range of thermal input power. Conventional systems are designed to work optimally for a nominal operating condition, while maintaining the ability to operate at off nominal and extreme operating conditions without damage to the system. For systems that operate in a narrow range of thermal power conditions, thermoelectric waste heat recovery system design is simplified. However, for applications that do have a wide range of operating conditions, designs typically exhibit overall average efficiencies that are reduced by approximately 20% or more compared with that achievable for the thermoelectric material operating at peak efficiency. Both cars and trucks consume significant fuel at low mass flow rates. Since the ultimate goal of waste heat recovery systems is to minimize fuel consumption, it is critical that the recovery system be designed to operate near peak efficiency over the range of mass flow rates that make a significant contribution to overall power recovery. Such performance capability is especially important in

city driving, and in hybrid vehicle applications. This paper describes a design concept that maximizes the performance for thermoelectric power generation systems in which the thermal power to be recovered is from a fluid stream (e.g., exhaust gas) subject to varying temperatures and a broad range of exhaust flow rates. The device is constructed in several parts, with each part optimized for a specific range of operating conditions. The thermoelectric system characteristics, inlet mass flow rates and fluid temperatures, and load and internal electrical resistances are monitored and generator operation is controlled to maximize performance. With this design, the system operates near optimal efficiency for a much wider range of operating conditions. Application of the design concept to an automobile is used to show the benef

8.外文期刊K. M. SAQR.M. K. MANSOUR.M. N. MUSA THERMAL DESIGN OF AUTOMOBILE EXHAUST BASED

THERMOELECTRIC GENERATORS: OBJECTIVES AND CHALLENGES

The potential for thermoelectric power generation (via waste heat recovery onboard automobiles) to displace alternators and/or provide additional charging to a vehicle battery pack has increased with recent advances in thermoelectric material processing. In gasoline fueled vehicles (GFVs), about 40% of fuel energy is wasted in exhaust heat, while a smaller amount of energy (30%) is ejected through the engine coolant. Therefore, exhaust-based thermoelectric generators (ETEG) have been a focus for GFV applications since the late 1980s. The conversion efficiency of modern thermoelectric materials has increased more than three-fold in the last two decades; however, disputes as to the thermal design of ETEG systems has kept their overall efficiency at limited and insufficient values. There are many challenges in the thermal design of ETEG systems, such as increasing the efficiency of the heat exchangers (hot box and cold plate), maintaining a sufficient temperature difference across the thermoelectric modules during different operating conditions, and reducing thermal losses through the system as a whole. This paper focuses on a review of the main aspects of thermal design of ETEG systems through various investigations performed over the past twenty years. This paper is organized as follows: first, the construction of a typical ETEG is described. The heat balance and efficiency of ETEG are then discussed. Then, the third section of this paper emphasizes the main objectives and challenges for designing efficient ETEG systems. Finally, a review of ETEG research activities over the last twenty years is presented to focus on methods used by the research community to address such challenges.

9.外文会议J. B. Posthill.J. C. Caylor.P. D. Crocco.T. S. Colpitts.R. Venkatasubramanian High-

Temperature PbTe Thin Films for Use in Cascade Thermoelectric Power Generation

PbTe-based thin films were deposited by thermal evaporation at temperatures ranging from ambient temperature to 430 ℃ on

thermoelectric material for a mid-temperature stage in a cascade power generation module. Pure PbTe, PbSe, and multilayer PbTe/PbSe films were investigated. All films deposited on different vicinal GaAs (100) substrates were found to be polycrystalline when deposited at 250 ℃ or lower. A subtle effect of substrate orientation and multilayer periodicity appears to contribute to the more randomly oriented polycrystallinity, which also lowers the thermal conductivity. These results are compared with PbTe epitaxial

results on BaF_2 (111).

10.外文期刊AARON D. LALONDE.PETER D. MORAN Synthesis and Characterization of p-Type

Pb_(0.5)Sn_(0.5)Te Thermoelectric Power Generation Elements by Mechanical Alloying

A mechanical alloying (MA) process to transform elemental powders into solid Pb_(0.5)Sn_(0.5)Te with thermoelectric functionality comparable to melt-alloyed material is described. The room-temperature doping level and mobility as well as temperature-dependent electrical conductivity, Seebeck coefficient, and thermal conductivity are reported. Estimated values of lattice thermal conductivity (0.7 W m~(-1) K~(-1)) are lower than some reports of functional melt-alloyed PbSnTe-based material, providing evidence that MA can engender the combination of properties resulting in highly functional thermoelectric material. Though doping level and Sn composition have not been optimized, this material exhibits a ZT value > 0.5 at 550 K.

引证文献(5条)

1.王国文.王秀峰.于成龙.江红涛.李金换.陈思涛梯度热电材料的研究进展[期刊论文]-材料导报 2007(7)

2.ZHOU Min.LI JingFeng.WANG Heng Fabrication and property of high-performance Ag-Pb-Sb-Te system semiconducting thermoelectric materials[期刊论文]-科学通报(英文版) 2007(7)

3.张建松热电薄膜氢气传感器中催化剂的研究[学位论文]硕士 2007

4.栾伟玲.毛顺杰.涂善东.高濂.郭景坤锶掺杂铅酸钡陶瓷的热电性能[期刊论文]-硅酸盐学报 2006(2)

5.毛顺杰Ba<,1-x>Sr<,x>PbO<,3>热电氢气传感器的研究[学位论文]硕士 2004

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